Reactions of f-Butyl Peresters, XVIII Peroxyester Reaction of f-Butyl N,N-Dimethylperoxyamidate
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چکیده
In the past [1-3], most frequently used model substrates for the peroxyester reaction included, among others, hydrocarbons containing activated hydrogen atoms, such as, cyclohexene, and ethers, such as, tetrahydrofuran. Peroxyamidate 1 (R = N(CH3)2) of acceptable purity was prepared in molar quantities by an improvement of the procedure reported by Pedersen [4] utilizing the reaction of N,N-dimethyl carbamoyl chloride (4) with £-butyl hydroperoxide in the pres-
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